Don't worry about it. Use the powder up after patching the hole. Air has water in it, it is called humidity. Water is a polar covalent molecule, which means it acts ionic, even though it is not an ionic molecule. The oxygen end of water has a charge, and when it lands on nitrocellulose it breaks the double bonds, just like ionic molecules. It also wicks nitroglycerine to the surface which spikes the pressure curve. Nitroglycerine also attacks nitrocellulose which is why double based powders have less than half the shelf life of single based. A little bit of air exposure is not bad, years of it is, and especially real humid air exposure.Don't soak your gunpowder in water.
Temperature is the worst normal environmental condition for gunpowder, gunpowder breaks down exponentially faster as temperatures increase. So don't store your gunpowder or ammunition in the attic.
and combustion pressures rise as gunpowder ages
there is a lot of information out there on this, but the shooting community not only does not want to know, many actively deny that gunpowder or ammunition ages. Humans are quite irrational, regardless of what they say. Humans only see what they want to see.
I believe the reason many shooters think gunpowder lasts forever is that they think they are immortal, and therefore, so must be their ammunition and gunpowder. And if either are not immortal, that blows their delusions of living forever. I can tell, spiking their delusions of shared immortality will cause some to feel that I have personally murdered them. Hence, denial goes to angry denial. It is scary.
This is an interesting lecture on Willful blindness
https://www.ted.com/talks/margaret_heffernan_the_dangers_of_willful_blindness#t-862866