I don't know if a .327 reamer will "clean up" a .30 chamber but you don't have to neck it down, unless you just want to use .308" bullets.
To follow up on CraigC's point, I don't think a .327 reamer will do anything in a .30 Carbine chamber. I just tried dropping a .327 cartridge in my .30 Carbine Blackhawk. It dropped in easily, appears to head space correctly, and the cylinder rotated without binding.
I do have a New Model .30 Blackhawk, but it appears to be a transitional model, with chambers cut to recess the case heads, as was done with the Old Models. There is a bit of a chamfer on the chamber mouth, and the case rim appears to be headspacing on this chamfer. It might be interesting to see if the .327 rim will headspace correctly on a current production cylinder.
I suppose one could try to size some .327 brass with a .30 die, and load with .308 bullets. As eluded to, the back end of the case would be poorly supported. The rear of a .30 Carbine cartridge is .356" diameter, where the full body of the .327 is only .337" diameter. It may bulge the case just slightly, but not to the point where I expect to see a catastrophic failure.
Here you can see .327 on the left and .30 on the right of the cylinder. I expect I could fire them, just as people often chamber and fire .32-20 in .30 Carbine revolvers.