Lets talk about Agnotology
https://en.wikipedia.org/wiki/Agnotology the study of culturally induced ignorance or doubt. In short,
why don't you know, what you don't know?
I think the ignorance about gunpowder and thus, ammunition lifetime, is primarily due to two factors: Firstly there is no profit educating shooters that their ammunition/gunpowder has a finite (though unpredictable) lifetime. In an economic system based on consumption,
there is no profit to be made educating people on what not to buy. Secondly,
no one wants to hear it. Humans have an infinite capacity for self deceit and shooters firmly believe that they are going to live forever, and therefore, so must their hoard of ammunition. Both of these beliefs are quite false. At some time in the future, both you and your ammunition are going to be dust, but you really, really, don't believe this. The human mind only sees what it wants to see, so most reading this, will ignore this because it conflicts with their belief systems.
What the OP has not mentioned is the age of his ammunition. Ammunition is loaded with gunpowder, a high energy compound, which from the day it leaves the factory, is breaking down to a low energy compound. As I previously wrote, the lifetime of gunpowder is unpredictable, ammunition companies will only warrant their stuff for ten years, and ammunition near 20 years old is getting long in the tooth. Heat incidentally, is the primary enemy of gunpowder. Deterioration of gunpowder follows an exponential function when exposed to heat. That is, the hotter it is, the faster it breaks down.
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Now I have heard all those people shooting 100 year old ammunition, and I will say, shoot enough of that stuff, and you will blow up whatever firearm you are shooting it in, but I do not want to spend time on this unfortunate and undesirable aspect of old gunpowder.
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As gunpowder breaks down, it releases NOx,. NOx is a spectrum of nitrogen oxides, I think all of which are highly oxidizing, nitrogen dioxide is particularly irritating, (that's the red stuff in the picture) and if your gunpowder is outgassing NO2, get the stuff out of the house before it autocombusts. But I do not want to spend time on this unfortunate and undesirable aspect of old gunpowder.
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What I will address is that NOx, particularly the NO2, that is released from old, deteriorating gunpowder, will attack brass.
These are my cases, all cases ruined by old gunpowder.
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Someone else's brass:
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Gunpowder deteriorating in the can
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The lifetime of gunpowder is so unpredictable that first world militaries spend lots of money paying ammunition technicians to monitor and inspect their munitions stockpiles, and toss out the stuff that is just on the cusp of going bad. This is either a 1968 or 1969 chart, don't remember exactly.
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Second and third world countries are so financially broke that they can't afford surveillance programs and so they allow their old ammunition to age to the point that their Munitions Depots have this unfortunate habit of exploding. The frequency is about one a month, somewhere in the world. Big badda boom!
As I wrote earlier, the OP did not state how old his ammunition was. So, I am going to make a jump of faith and say, the OP's ammunition is old. Old enough for the gunpowder to be breaking down, outgassing NOx, and the case neck's are cracking. Is this dangerous? Could be. We are in the realm of trying to estimate how dangerous is it to fly in a plane with a turbo fan jet engine that has cracks in the blades. That's not an easy answer. There are known examples of airplane crashes when turbo fan engines came apart, and before the planes flew, it was known there were cracks in the blades. I was told that every flight, after the first flight, of a space shuttle, there were cracks in the turbo pump fan blades. Luckily, for the turbo pump engineers, the two Space Shuttles that did blow up, did not fail due to cracked turbo pump fan blades. The astronauts died because of other known problems.
When gunpowder is deteriorated it experiences burn rate instability. A fancy set of words, but, old ammunition burns "funny". Not funny "Haw, Haw", but unpredictably. That is never good, and as gunpowder ages, so do combustion pressures. Lots of guns have blown up due to old gunpowder, but the owners, don't know why. Back to Angnotology again.
Why don't you know, what you don't know?. The most likely outcome of the OP shooting his old ammunition is that every case experiences a brass crack somewhere. I predict that some of his cases will show high pressure indications. If he is lucky, he won't have a case head failure. Maybe you can see, some of my 223 Remington brass split in the exposed case head, venting gas inside the mechanism. Nothing bad happened, but it could.
I don't always follow my own advice, and someday I will suffer the consequences, but I will recommend, that if factory ammunition is regularly splitting case necks, that the owner of that ammunition stop shooting the stuff. The safest thing to do is pull the bullets, save the bullets, dump the powder out on the lawn, and throw the brass away. The brass is ruined, the gunpowder is ruined, but bullets can be used.