For serious use I mean to actually go hunting with or some such. Not like the phosphorus youtube vid Lee Roder is referring to where it would be dangerous to implement.
Frogo, what machining? I'm referring to "reloading" primers, not making them from scratch. And for the record, not making them in bulk either. Just making a few with precision when factory ones cannot be had...or just for the fun of it. Cookbook chemistry can be fun.
navyretired, you swag? I understand spent primers are good for gas checks, and 22LR jackets for .223s.
Hum, a potassium chlorate, charcoal, sulfur mix might do the trick as apparently this was the mix of WW1, with WW2 being potassium chlorate, antimony sulfide, lead
thiocyanate, and Trinitrotoluene. Tricky stuff that last bit -- got to be careful when adding that third nitrogen. The WW1 mix produces potassium chloride, but this wouldn't be an issue for the purpose defined above.
Match tips with graphite i.e. pencil lead as a stabilizer may be an interesting "from household items" primer, albeit probably still unsafe.