A rifled-slugs is designed for a smooth bore shotgun. They get the name rifled-slug from the angular grooves in their sides, that look like rifling marks on them. The groove impart very little if any spin and are there primarily to aid the soft lead slug swaging through any choke, up to and including full, safely. Rifled-slugs are primarily a drag stabilized projectile, using a forward center of mass and the trailing lead skirt in a manner similar to a shuttle cock from badminton.
As for the particulars of using rifled slugs with black powder muzzleloading shotgun I have very little experience. It should work but I have no first hand experience. A round ball might be easier, that said a good rifle slug would probably be more accurate.