It's not unreasonable to suppose that not every gun will have fixed sights that are perfectly regulated right from the factory.
And since your pistol is a Belgian Centuar, I'm figuring that you'd probably rather not permanently alter it by deepening its hammer notch or by installing a drift adjustable front sight.
I can only think of a few other options.
One is to learn by trial and error to very slightly cant the piece when you're aiming and firing to in effect alter the windage.
It's possible that this slight adjustment could be accomplished by canting the revolver just a few degrees to the right, i.e. - at about the 12:30 position instead of the 12:00 position.
By aiming that way the muzzle will be slightly offset which will create a tendency to slightly move it the desired amount to the right upon firing.
No one holds their muzzle perfectly still while aiming or while firing anyway since it's really a physical impossibility to accomplish that with any sort of absolute repeatability. The best that any shooter can hope to strive for is to keep their sights aligned to impact
around the center of the target black when they're pulling the trigger.
Beside canting the gun which is not the ideal method, I can suggest finding a way to temporarily alter your front sight which I speculated about in post #4 of another thread:
http://www.thehighroad.org/showthread.php?t=524516&highlight=front+sight
Or lastly, you could deepen the notch of a replacement hammer to see how that works without making any permanent changes to your original part
that could end up devaluing your Belgian Centaur.