Zonie said:If you look thru the space between the frame and the bottom of the cylinder you can probably see the cylinder locking bolt sticking up into the cylinders slot.
If you can cock the hammer part way you should see this bolt retract into the frame. If it doesn't retract the problem is either with the bolt or the cam on the hammer.
To find out which you will have to remove the rear grip strap and wood grip and then loosen the screw that holds the mainspring to the front grip strap/trigger guard.
With the screw loosened (but not removed) rotate the mainspring out from under the hammer. Then remove the three screws that hold the triggerguard/front grip strap and remove it.
Removing the trigger/bolt spring is a matter of removing the screw. Make a sketch of how that spring was installed so you don't put it in backwards when you reassemble the gun.
Removing the bolt screw should allow the bolt to drop free of the cylinder. That should free it so that it can rotate freely.
The cylinder locking bolt that you just removed has a leg on it that is supposed to engage a cam on the hammer. If that leg is broken it would explain why the bolt isn't releasing the cylinder
dennisA said:As to the cylinder being bound up, if thet is the problem, If it hasn't been used for awhile and maybe was not properly cleaned or stored you might have some corosion freezing it to the arbor.
Dissasemble it as far as you can to make sure that is the problem and not something in the works like scalper said. If the cylinder is frozen a good soak with penetrating oil will most likely work if not the judicious application of some heat to the cylinder and more penetrating oil should get it.
Wet Willie said:If there is a stuck cap fragment, usually you can wiggle and twist the cylinder until it drops free.
Another possible cause of a locked-up cylinder is that a capped but very small/no charge was placed, causing the ball to move part way into the forcing cone. Even after removing the wedge, the cylinder remains stuck to the barrel.
You can check this condition by sight: if there is no space between the cylinder and barrel, this may be the condition. If there is a ball stuck, you can pound it back (wood or brass rod) into the cylinder and remove the barrel. (PLEASE don't use a screwdriver!)