Alot of rearsenal'd Mosins have cosmoline dryed in their chambers, and the fit feels like tight headspace. Its hard to see the stuff, as it shines and is what is constricting the chamber but a drill, 20 gauge brusha nd carb cleaner will get it out.
When thers cosmo in a recently uncrated Mosin chamber, it makes for a tight chamber, often leading one to think the headspace is too tight. That cosmo has been there for 60+ years, and can be hard to remove. They did that , because if the chamber is bad, its useless.
Otherwise, a reaselnal'd Mosin will be in spec, and inspected and given one of a myrid of inspection marks, this included test fireing and head space adjustments BEFORE it was accepted, preserved and crated for WWIII
In an armoie, a chamber reamer would have done the job if swapping bolt heads didnt fix the problem.
Its a rimmed cartridge and head space issues are settled on the thickness of the rim, not the shoulders length, and a bolt head swap can make that adjustment.