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Found a reference to a .56 colt cartridge made of animal gut. Really 56 caliber?
"ANIMAL GUT CARTRIDGE - A primitive combustible cartridge consisting of a tubular sheath or sack filled with black powder which is attached to the base of a conical bullet. The sheath is made from thin, treated animal gut and is reasonably moisture proof. See William Mont Storm patent #33,611 and Hotchkiss patent #34,364. Most were made by D.C.Sage and found in .36, .44, and .56 Colt caliber as well as a few others. "
"ANIMAL GUT CARTRIDGE - A primitive combustible cartridge consisting of a tubular sheath or sack filled with black powder which is attached to the base of a conical bullet. The sheath is made from thin, treated animal gut and is reasonably moisture proof. See William Mont Storm patent #33,611 and Hotchkiss patent #34,364. Most were made by D.C.Sage and found in .36, .44, and .56 Colt caliber as well as a few others. "