>So, when I am loading, and get the same velocities as in the manual, it is a good assumption that I have reached the same pressure levels.
Good assumption, just that it doesn't work in the real world. One would think that a given pressure would produce a given velocity, but I have seen slow and fast barrels where the same pressure produces very different velocities. Now, maybe, if you chrono factory ammo and then use the chrono with all the other pressure sign variables to work up loads in that gun, you MIGHT be able to do what you think you can. Have you seen any proof of this to risk you gun and health on?
So far, except MAYBE in long-range rifle match shooting, I have not even seen any correlation between S.D. of velocity and accuracy, when we all "know" that the more consistent ammo should be more accurate--yet, looking at all the results in the magazines, the low S.D. rounds are so often the least accurate.
I do know, from actual pressure testing I had available once, that I could get 9x19 well above the manual's max load and exceed the max velocity by 100 fps and still be below the max pressure. Likewise, I had some loads that hit max pressure well under the manual's max load or the max velocity shown. I had a 110gn bullet at 1520fps and 33ksi in test facility's gun (5" barrel).