Thank you both for your replies, yes castbullets has some good threads that touch on this and it sounds like the .27 caliber powder blanks fit the chamber well since the .25 Stevens cartridge has a .27 chamber and an internal bullet, unlike the other rim fires which use a heeled bullet of the same diameter as the case. So, that is an option. Another is to buy some actual .25 Stevens short ammo (you can find a box on gunbroker for around $90 last time I checked). And then just use those, bore out and countersink the back after firing to accept a .22 rim fire case and reload same as I had proposed with the .25 acp. I may go that route as what bcrider stated may be the case, I.e. the bore is trash. In which case I might not even get through a box of ammo before shelving it or choosing to reline etc. I think I’ll spend the $100 or so to get a box of actual .25 Stevens short and worst case I took a few shots and spent some money, and best case I have brass that I can do something with to keep her running.
As a side q, what are the thoughts with jacketed ammo and old presumably soft barrels? If I did go down the .25 acp route, they would have the jacketed bullets.