I don't know the "guns" as much as the cartridges. As a general rule, the cartridge is designed before the gun.
Americans have been blessed to live in a country with vast natural resources, there are metals we don't have, such as nickel and titanium, (and rare earths). The US has/had copper and so America used copper in making expensive brass cartridge cases. One other blessing, it has been a while since large portions of this Nation were occupied by foreign invaders. Both Russia and Germany experienced this during WW2. Take a look at this, from a WW2 book, about the number of soldiers and equipment Russia lost in the first year of the German invasion.
add into that the land, rail lines, mines, factories, that were also off limits, because the nasty Germans took them too, and you can see that Russia was really over a resource barrel. Incidentally, these numbers on the picture, late in the war, I will bet the German losses looked something like that.
The Germans were over the resource barrel very early and needed to conquer land to get the resources necessary to continue a war time production. I do know that in WW1 German was stripping France and Belgium of all the copper and brass that it could find. In occupied Belgium, civilians had to provide a complete list of household items. The Germans than took that list, knocked on the door of Belgium household and conducted an "inventory inspection". Items not on the list were confiscated as contraband. That also included the items buried in the Garden. You think the Germans did not catch on to that early in the war? Then, after all those copper pans and brass items were taken, the Germans then came in and took copper/brass items on the list! Worthless war time money was given as compensation. It was a deliberate and well planned campaign to strip occupied areas of everything of value to the German war effort. And yet, even taking all the brass, copper, bronze they could, the Germans never had enough for cartridges and artillery shells.
So it was, during WW1, the Germans made the first steel case 8 X 57 mm Mauser cases. Which they found, they had to coat the steel case ammunition with wax. Wax works very well as a lubricant, under the temperatures and pressures of combustion the stuff melts and becomes a liquid. Unwaxed 8mm ammunition had a propensity to stick in the chamber. From Dieter Storz's book: Rifle & Carbine 98: M98 Firearms of the German Army from 1898 to 1918,
https://www.amazon.com/Rifle-Carbine-98-Firearms-German/dp/390252605X one company made 26 billion “iron case” 8 X 57 Mauser ammunition during WW1. Dieter Storz has an extensive chapter on the "iron case" 8 mm Mauser cases. Iron was not used to make cartridge cases, the book is translated from German and translators can miss subtleties.
I have no doubt the Russian designers of the 7.62 X 39 well understood the scarcity of strategic materials during a war and that is why the 7.62 X 39 round was designed with steel as the case material. Brass case 7.62 x 39 exists, because brass is still the best material to make cartridge cases, but I have seen much more military steel case than I can recall any military brass case. I am sure someone has a few brass military rounds.
Incidentally, the Chinese are pretty smart people, and they have put their best designers to make really good military cartridges and rifles. This is an example
This round has a lot of taper, operates in the lower 40 kpsia range (which is just great as high pressures causes more problems than it cures) and has a thick rim. No doubt the Chinese examined the expansion and contraction of the case in the chamber, decided on an optimum clearance as the pressure curve dropped during the residual blowback period, and carefully determined case hardness necessary to ensure proper contraction clearance. The 5.56 case, even with brass as a material, drags during extraction. This is called "extractor lift", where the bolt retracts, but the case stays in the chamber. Surely Chinese Production Engineers were brought in to ensure that a steel case of that dimensions and hardness requirements could be made with state of the art production equipment and facilities.
As an example of ignoring production issues, the early 5.56 cartridge, the pressure curve requirements were tighter than state of the art gunpowder production technology could hold. The powder manufacturer had to make, lets say, 10 lots of powder, go out and sample which lots could meet the pressure curve tolerances, and scrap the non conforming lots. Might be five, might be all 10! Since meeting the pressure curve requirements was only by chance, this is just one example of what happens when a wildcat is adopted as a military round. Which, incidentally, the 223 Remington was. And that is why so many have had issues with steel case 223, the drag is even worse.