GONRA remembers pulling an Olde Fashioned WHITE PHOSPHORUS incendiary bullet from rifle caliber cartridge case and noting a wisp of smoke coming out. Phosphorus Pentoxide.
(Don't Panic - today's incendiary ammo that we find a Gun Shows etc.
is Perfectly Safe - no WP in it!)
Lucked out - not enuf heat to lite off the powder in the cartridge case.
If powder HAD ignited, would have just made a flash, no real damage,
assuming one had their Safety Glasses on!!!
Ammo was a Collectors Item - pretty sure
8mm Mauser caliber and WW II Japanese manufacture.
Apparently a little WP got out thru the soldered weep hole over years of storage, temperature cycling, etc. loosening up the solder plug.
Could have leaked out thru bullet base too? ??? Who knows?
When I pulled the bullet, a little WP was inside case neck
or on the powder.
Tiny bit of WP quietly burned in the air, didn't even see a flame!
One can probably make a credible story for a WP rifle caliber ammo failure mode (weep hole fails, WP leaks out in really hot weather,
ammo is cracked case neck olde stuff, air gets in and off it goes...)
that causes a ammo fire, but its REALLY DOUBTFUL the fella had WP incendiary smmo.
10-20 years ago some guy was selling shootin' quantities of WP type rifle caliber (may have been Italian 7.7mm version of .303 Britich?)
incendiaary ammo in the Shotgun News. Listed as "wet pack".
To me, meant he was selling it packed in water, because of "suprise ignition" issues. Never knew the facts of course - didn't buy any - "wet pack" was scarey...
Guess you had to dry it off then try to shoot it. Hmmm.
Believe (hope) its safe to store WP ammo collector items in air tight ammo boxes.
Again, its really doubtful the fella had WP ammo,
but its the only way I can figgerout how ammo can "go off on its own".