This is right up there with that thread in the rifle section that asks "can I fire .38 Super in a .357 magnum lever rifle" or the myriad of threads aking "can I shoot .45 Colt in my .410"?
Use the gun as advertized. You wanna burn smokeless, I can recommend .308 or many other rounds. Yeah, I shoot bullseye in my Super Companion, NAA actually recommended it until the ATF got on their case about it, but the problem with smokeless in a big chamber is that to produce an equal pressure to BP, one must weigh the charge to the tenth grain. It does not work well with volumetric measurement. Oh, I've used those Lee scoops in the past, but with REDUCED charges and they aren't very consistent.
Think of it this way if no other way, you might survive a double charge of BP if you're shooting, say, 70 grains charge, but a double charge of 2400?
Nothing goes in MY BP rifles, but a suitable substitute since I can't readily buy BP anywhere near abouts. If it's performance you want, try 777.
And, well, I was already warm.
It was 41 degrees this morning when I walked out to check my hog trap. I know that's not cold to northerners, but I did get a little chilled bein' a south Texas boy.