Unique "should" burn cleaner than that if you bring the pressure up. I load a lot of Unique and don't get those results. I use it in 357, 41, 44, and 45C and after a couple hundred rounds I have nowhere near that much residue. I don't load max but I do get kinda close. I have never used PP but IF I could find some I would like to give it a try.
I load 7.5 g of Unique with a 158 g SWC and get good results. I've got data that says that is close to max and data that says it's a tad over for a 158 LSWC but it works good for meI load 6.6 unique under a .358 158 LSWC 18b. The bullet seems to bump out well and seal the barrel. I wouldn't think that is too light as to burn dirty. It's my most accurate load. Sounds like the PP is going to do the same ?
I know this may not be what you want to hear but I load power pistol in 38 special. I load 125gr hp at 6.2gr and 158gr cast SWC at 5.5gr or 6.0 for +p.