However, the total pressure curve is different than straight chamber pressure. There is a reason that .357 out of a saddle gun is faster than out of a 6" revolver. There is more time for the overall pressure curve to act on the projectile and accelerate it.
There is a reason the military's put 26" to 30" barrels on rifles in the old days, it was to get maximum velocity out of the available powder. They wanted to take maximum advantage of the pressure curve and use all the powder.
Chamber pressure is related to initial ignition and the spike in the pressure curve related to the smallest volume. Once the projectile starts moving, the spike is over as the volume increases. That does not mean that all pressure is gone, it may be less than initial (chamber pressure), but it is still higher than atmospheric and friction, so it still accelerates that bullet.