What do you mean by "learn it"? Can you clarify your question a bit??
Is this what you are looking for?......
DA/SA basically means that the first pull of the trigger (double action e.g. BACK then FORWARD action of the hammer) will have MORE LBS. OF PULL to cycle the hammer back before it then comes forward again and strikes the firing pin. How many LBS. of pull will depend on the firearm, manufacturer, style, any custom trigger jobs, etc. After that, the action of the slide coming back will reset the hammer into SINGLE ACTION, meaning that the hammer will then already be back and ready to be fired again. Now, the LBS will be much less and the trigger "travel" may be longer to get to the point of release. WORK ON FINDING THE "reset" POINT of the break for better control and consistency. On the last round, typically, the action will then stay open and be ready to fire again in SINGLE ACTION when the new mag is inserted and slide release puts the round into battery. If you don't chose to shoot (for whatever reason) many sidearms have a "decock" mechanism that will cycle the hammer back to "normal"(e.g. double action) but guards it from striking the firing pin. At this point the firearm will be in double action again.
For example, the popular 1911 style of firearms is SA ONLY, meaning that the hammer MUST be back to start with (if not you can pull on the trigger all day and it won't do a thing). This is usually coupled with a thumb safety, grip safety, or a combination of both (or none??).
IMHO....a DA/SA firearm should always start in DA mode, but I do hear stories of people intentionally cocking the hammer prior to firing. If you do this, be VERY AWARE of trigger discipline because, again, the LBS. of pull will be much less. I would advise against carrying a DA/SA for CCW in SA mode.
Hope this helps!!