My own measure, after tinkering with a Smith, is to dry fire it as fast as I can. If I can beat the trigger, time to go back in with a heavier rebound spring. It depends on lots of things, including the slickness of the inner works.
It's an interesting philosophic question:
I've maintained the rebound and main springs should be balanced, but what is "balanced"? I've established that metric myself by measuring the DA & SA pull weights on stock revolvers and concluding the springs are "balanced" when the DA:SA ratio is roughly 2.8:1. You can swap springs for a lighter pull (and I have), but the ratio remains the same.
OTOH, the issue with an imbalanced rebound spring is the reset, so a functional way to establish balance is whether you can beat the reset. If you can, for whatever reason, put a heavier rebound spring in.
I keep betting, hoping, that all is needed is for the gunsmith to put in
new springs from a kit and all will be well; that the parts were not
butchered by the previous owner
If the OP is experiencing pushoff, it ought to be fixed, of course. OTOH, the OP also indicated the SA & DA pull weights are 5 oz and 4lbs, respectively, yet the gun shoots reliably. Assuming the measurements aren't off, the gun might be the product of an outstanding gunsmith who really know what they were doing.
hmmm....coming back to the aforementioned DA:SA ratio of 2.8:1: The OPs SA & DA pull weights of 5 oz and 4lbs, and
that ratio is more like 13:1. The reliability and the pushoff could be explained simply by an uber-weak rebound spring. With an appropriate rebound spring, the SA and DA would come up quite a bit, yet it's the mainspring, which wouldn't change, which provides the power to the falling hammer. As far as the pushoff, the trigger sear is engaging the hammer notch by a cat's whisker. If the rebound spring is way too weak, there may be too little resistance to rolling the trigger clockwise (looking into the open lockwork from the right), resulting in pushoff. Maybe all it needs is a heavier rebound spring? A spring that gets SA to roughly 3lbs, ought to take DA to roughly 8lbs (DA:SA = 2.7:1) - I'd be interested to see what effect that has on pushoff, if any.