I had no problem with rifle, pistol, shotgun, or belt fed ammo kept in a vehicle while in Iraq during the summer. The temp(unofficially) got to 148F, and inside the trucks was hotter. The guys with belted 40mm had no reported ammo problems either, but didn't fire many rounds at all.
The weapons themselves got hot enough to burn skin- I needed gloves to operate my M249.
I see no problems with vehicles storage, besides basic security- especially if kept out of direct sunlight. I would keep chambers empty, however, for that and other(impact and fire in a collision) reasons.
If it makes you feel better, replace your vehicle ammo regularly. Peace of mind is worth more than current ammo costs. Plus, it guarantees you range time and practice.(wouldn't want that "heat degraded" ammo lying about)
Marksmanship is a perishable skill. Take any excuse to train that you can.