Jammin' Hawk
Hi Tim, and welcome aboard.
Do a quick check. Fire the one round and remove the empty...Return the cylinder to battery and see if it's locked up. If it doesn't, you may have one of two things at work. Tight headspace...with insufficient clearance between
the recoil shield and the case rim. When the round fires, the brass backs up
slightly and butts against the recoil shield...and causes it to drag.
Also possible that the chambers are tapered slightly, and will do the same thing, even with good headspace because the case backs up hard..hits the shield...and forms itself to the tapered chamber. The result is a lot like a drill chuck/tapered spindle. It wedges itself in place and can't move in either direction.
A small possibility that unburned powder gets under the ejector star,
and creates the same effect as the insufficient headspace condition...but it's not highly likely that it would occur with just one round.
Could also be a combination of any or all of the above, along with a slightly bent ejector rod. Easy to check for too. Just spin the cylinder and watch closely for wobble anywhere along the axis.
Either way, it's a job for Ruger or a revolver smith. If you can find the headspace specs for the Redhawk, you can use a feeler gauge to see if it's too tight.
Paging Jim Keenan! We need some headspace specs on this man's revolver!