Static Electricity and Black powder

Danaidh

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Good morning. This subject keeps being bantered about on the internet and poor information is passed around and repeated creating internet myths.

FYI:
I am not an expert on this subject. However, I do read about this subject and the following is a quote from the most notable guru on the science of all things black powder:


"There were some excellent papers written on this around the turn of the century in 1900. This was when a lot of powder plants were switching from water wheels to electric motors. The most informative paper came out of an incident in Germany. They found that it was nearly impossible to ignite grains of black powder with electric sparks. But dust in the corning and screening operations was very easy to ignite with strong electrostatic sparks. This ease of ignition involved small particles of sulfur given off by the processing of the powder in these operations. And this was before they realized they had to both ground the electric motors and move them out of the work areas onto outside building walls. The strength of the sparks needed to ignite the grains was far above what the human body or clothing could produce.

As to static in plastic bags or plastic bottle containers. The problem with the use of plastics was not the danger of a static spark. Simply that the light static charges built up on the grains of powder caused them to cling to the plastic. These plastic bags, etc, were supposed to be safely disposed of by burning. So you did not want a large pile of used black powder containers in a burn pile to be burnt. You did not want to be the guy heaving the match into the pile. Hoist with his own petard results."

Somewhere along the way I lost the report out of Germany on the sifting packing house explosion. Dated back to around 1910. They first tried to ignite grains of black powder with one of those big spinning wheel electrostatic generators. Those form charge strengths far above what man and his clothing produces. In the end they were able to ignite grains of black powder with a spark generated by a coil using 8 amps and 18 volts feed into the spark producing coil. This was their clue that any small static spark explosion had to relate to the dust in the building. The report stated that all electric motors must be grounded and with explosion proof wiring and switches They must properly ventilate the works areas to reduce dust levels. They described the accumulation of static charges in the air in the room with the machinery running. This report was used to show why any electric motors should be mounted and wired outside the buildings driving machinery by shafts running from the motors through the walls and then onto the actual machinery. Even as far as designing packing glands for the shafts where they went through the walls. That way there would be no dust laden stream of out of the shaft openings in the wall that might then be ignited by the motor mounted outside the wall. The lessons learned from this German experiment were then used when other machinery such as wheel mills were "electrified".


- Mad Monk
 
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Don’t ever, ever, take energetic materials for granted. Static electricity provides a spark, and that will create a fire. After that, who knows what fun will happen.

Three U.S. Army soldiers were killed and 16 others were injured when a rocket motor for a Pershing missile caught fire and burned as it was being unpacked at an American nuclear base in West Germany, U.S. You can read the report, this was a new missile, properly grounded in its container, and yet, it went off. The report states the most likely cause was electro static discharge. A spark.

Technical Investigation of 11 January 1985 PERSHING II Motor Fire

https://apps.dtic.mil/sti/pdfs/ADP005343.pdf

that is a Pershing rocket out of its container.

KNFkwGu.jpg


To increase your unease, a shooter I pulled targets with, he worked at Arnold Engineering Center when AEDC was first article testing a Pershing rocket. The rocket motor flamed out as it was being tested for thrust. Unburnt propellant fell 200 feet into the pit below. Based on the web, a Pershing has 16,000 lbs of propellant, I thought bud said there were 64,000 pounds of powder in the pit, I must have heard wrong. Maybe 6400 pounds?

Anyway AEDC had to get the powder out of the pit, bud was on the safety team and made his recommendations. What the authorities decided was to send men into the pit and cut the powder chunks with a wire saw, and hoist out the chunks. A wire saw has a wire instead of a saw blade, must be like a bow but with a metal wire. Apparently rocket motor propellant has the consistency of hard cheese. All that is known, is that that propellant ignited and killed a number of men in the pit. I only found a brief notice in a Tullahoma paper about a fatal accident at AEDC, no details.

People get killed on these National Test ranges, and you don't have a need to know. Which is why, you don't know. But energics go kaboom all the time on military ranges. You just don't hear about the incidents.
 
Pretty much any suspended dust is an explosive hazard in the right concentration, but there is unlikely going to be a suitable concentration suspended in the air in any common home reloading shop or target shooting /hunting usage.
I'm not worried about static and BP but I'm not going to keep hundreds of lbs of it under my bed either.
 
Read what I said back in 2020. I am not going to type it all out here.

Bottom line, the graphite coating on modern Black Powder will probably allow a static charge to flow harmlessly over the surface of the powder grains without encountering enough resistance to generate enough heat to ignite the powder.

But just to be safe, I prefer to load my Black Powder cartridges in the summer, when the humidity is relatively high, vs in the winter when the air is drier.
 
Pretty much any suspended dust is an explosive hazard in the right concentration, but there is unlikely going to be a suitable concentration suspended in the air in any common home reloading shop or target shooting /hunting usage.
I'm not worried about static and BP but I'm not going to keep hundreds of lbs of it under my bed either.
I don't know how much dust is needed to cause an explosion. People's level's of cleanliness also vary. But dust does cause explosions, particularly in industrial environments, and regularly. It was an eye opener to read some of the kaboom's caused by dust.

Dust Incident articles: https://dustsafetyscience.com/articles/

Dust Safety Hazard Podcasts: https://dustsafetyscience.com/category/podcast/

Dust Safety Hazard Textiles

Textile Explosion Case Studies https://dustsafetyscience.com/textile-industries/

The paper reviews some case studies of dust explosions in the textile industry.

The first one they mention is a 1987 linen dust explosion Harbin, China. On March 15, 50 people were killed and 177 injured in a series of explosions so violent that the seismographic records registered nine peaks. There was one primary explosion followed by eight secondary ones, all of them so devastating that 13,000 square meters of the factory were damaged.


The explosion originated in one of the nine dust collection units. Although the ignition source was not identified, the authors hypothesized that electrostatic discharge or a localized, glowing nest of material ignited the explosion, which propagated from the dust collector through the ductwork and involved all the other units in the carding section. The pressure lifted the dust layers on the floor, causing secondary explosions in the carding and spinning sections and underground textile stock areas.

The second case study referenced in the paper is a 2001 nylon flock explosion in Italy. This incident, which was covered in
Episode #76, started in a dryer after it had been shut off so that threads could be retied. When the dryer was powered back on, the resulting explosion propagated back to the dust collector, and the other dryers and blew out the side of one of the ducts. There were also flash fires that injured three workers.

The third incident covered is a 1995 flock fire and explosion at Malden Mills in Massachusetts. 27 people were injured and over 40% of the plant was damaged. The cause was an electrical spark created by the electrostatic grid system at the beginning of the production line.

The last case study covered in the paper is a 2001 wool dust explosion in Italy. This facility, which carried out washing, carding and wool combing activities, was full of dust containing vegetable residues. When smoldering combustion started in the basement, where several filtering cells were present, a huge deflagration occurred and caused a 20 to 30-meter flash fire, which was fueled by the layers of dust. In this case, the impurities and oil vegetable residue on the wool fueled the explosion.


One podcast: https://dustsafetyjournal.com/issue3/

Dust Safety Science Podcasts:


An OSHA poster, can't link to the image:

https://www.approtec.com/wp-content/uploads/2016/08/OSHA_combust_dust.pdf

Black powder won't kaboom due to static electricity but peanut butter dust will? Why should I believe this?
 
...Black powder won't kaboom due to static electricity but peanut butter dust will? Why should I believe this?

If the BP is in powdered dust form and in a suspended cloud in the air it will kaboom as long as there is also oxygen, and a sufficient ignition source which doesn't take much in that scenario.

Folks familiar with Class II hazardous locations won't be surprised.
Suspended dust can be quite dangerous
 
There was an explosion 15 or so years ago at a sugar mill in my town that killed a few people. Suspended dust was the cause that was ascertained.

We used to this as kids. Get some powdered non-dairy creamer and sprinkle it over a lit match. You have to use the right technique to get the creamer granules a bit spread out but it will make a fireball.

Here.

 
While I was still working, management hounded us working stiffs with all sorts of safety protocalls.
One of the biggest was grounding & bonding. Our plastic containers all has a threaded steel plug to connect to.
Now later and
in real life, an old friend was pouring gasoline from a plastic gasoline approved vessel
into his four wheeler (which also has a plastic fuel tank) when all of a sudden everything was engulfed in flames.
He was out in his machine shed, with no electricity. It had to start from static electricity.
When I was younger I would not have believed it, but I guess with age I've become more open to such things.

AntiqueSledMan.
 
A gentleman at CT Muzzleloaders has experimented with black powder and static electricity:



In 1963 i was member of the 24th Ord Det (EOD) in Korea. The ammunition battalion we were assigned to ran a maintenance facility for the Nike Hercules air defense missile. A technician was killed when a Nike Hercules booster motor igniter fired while being carried to the storage building.
 
Those photos are nothing new, I have been seeing them for years.

The key, as I mentioned in 2020, if you bother to read it, is that modern Black Powder grains have a coating of graphite. The graphite is probably there to make the powder flow easily through a powder measure, but the added benefit is the graphite coating conducts electricity better than the powder grains themselves. Also, if you bother to read what I said back then, Black Powder, or really anything else, ignites when it gets hot enough. The graphite coating on modern Black Powder causes the electric charge to travel more easily over the surface without encountering enough resistance to create enough heat to ignite the powder.

Check out what I said about the Thunder Boxes in the 1700s. A spark most definitely ignited the powder in them.

Please go up to post #3 in this thread and click on the link.
 
I am all about safety. I read lots of things to make sure I am smart and safe. So I use tools and techniques to avoid static electricity. I do not worry about static electricity and BP. Could it happen? Yes. Likelihood? Very unlikely. There are risks to everything. If people were blowing up and dying from static electricity igniting BP, we would have more horror stories, examples and procedures of what not to do. Be smart and minimize all risks to the maximum extent possible. There is no such thing as eliminating risk, only mitigating it.
 
While I was still working, management hounded us working stiffs with all sorts of safety protocalls.
One of the biggest was grounding & bonding. Our plastic containers all has a threaded steel plug to connect to.
Now later and
in real life, an old friend was pouring gasoline from a plastic gasoline approved vessel
into his four wheeler (which also has a plastic fuel tank) when all of a sudden everything was engulfed in flames.
He was out in his machine shed, with no electricity. It had to start from static electricity.
When I was younger I would not have believed it, but I guess with age I've become more open to such things.

AntiqueSledMan.

Probably summertime and the gas was probably stored in the shed. Lotsa fumes there. I used to do this as a teenager to freak people out. Drop a lit cigarette into a Coke bottle with some gas in it. All it does is put it out. I'd thump a lit cigarette into a five gallon open top bucket full of gas. Pour the gas out of the bucket and let it sit in the sun for awhile and thump a lit cigarette into it and it will blow up.
 
Yep, gasoline fumes are easily ignited.
Liquid gasoline not so much.
Similar to BP in that it takes more energy to ignite BP in its solid form than when suspended in the air as dust.
 
Read what I said back in 2020. I am not going to type it all out here.

Bottom line, the graphite coating on modern Black Powder will probably allow a static charge to flow harmlessly over the surface of the powder grains without encountering enough resistance to generate enough heat to ignite the powder.

But just to be safe, I prefer to load my Black Powder cartridges in the summer, when the humidity is relatively high, vs in the winter when the air is drier.
I concur.

Graphite is a good conductor of both electricity and heat, because of it's molecular structure (IIRC), and thus has a low impedance value. Low impedance means that current flowing through it is not entirely dissipated as heat.

An example of something that purposely has a high impedance value in order to heat up would be NiChrome wire, typically used in modern E- cigarettes or things like foam knives.


Sorry, whenever the topic of electricity is brought up I usually have something to say. I've spent years chasing an education in electrical engineering.
 
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