Wow, lots of info flying around while I was at work.
Fred, the lee key slug mold has the base pin integral with the mold, it's not a separate piece that slides in the bottom. So the opportunity to pre-heat it does not exist.
243, it sounds like you WERE trapping air. One bitch I have with lee, as far as their molds go, is the vent lines of the faces of the blocks are very shallow. Another thing, the sprue plate should NOT be in hard contact with the top of the mold. A very small gap is what you want, that allows air to escape that's being forced out of the cavity by the lead. This results in better base fill out. If you were holding the sprue plate hard against the top, then you took away that venting between the sprue plate and mold.
If I ever try holding the mold against the spout to cast pure lead, I get finning. IOW the lead travels into the vent lines looks like a cactus!
If I really need pure lead boolits, I use a lyman bottom pour ladle. it holds about 8 ounces of lead, plenty for even the biggest mold. The head pressure is less that the whole 20 pound pot full of lead, so no finning, but still well filled out boolits.
Sometimes I cheat! I put ½ to 1% tin in the pure lead. It lowers the temp that it melts at, and vastly improves the flow ability of the lead. AND contrary to what most believe, it does not harden it much. In fact it makes it tougher, which interprets into the slug being able to withstand acceleration better.