Yes Brownell's carries several crowning tools, the cheapest hand tool being $150 bucks.
http://www.brownells.com/.aspx/pid=18282/Product/BRASS-ONE-CALIBER-SET
For a one-time job on a mil-sup rifle?
Go to any hardware store and buy a large round-head brass screw, and a tin of 240 grit lapping compound.
Chuck the screw in an electric drill, apply the lap to the muzzle and screw head, and gofer it.
Keep the drill moving in oval circles and the round-head brass screw will lap a perfect crown.
With that said, many Mosens have pretty serious muzzle wear from 90 years of steel cleaning rods. But that wear is inside the muzzle, and re-crowning will not help anything at all.
The answer then is to counter bore the muzzle about 1" deep with a drill slightly larger then the bore.
The drill will leave a perfect crown inside, just not outside on the end of the muzzle.
For best results, I get someone with a lathe to do it.
rc