RCModel has a good primer pick he can post here- hopefully he does, that may help.
Federal rifle primers are by and large silver.
Remington and Winchester are by and large gold.
Remington factory primers seem to have a different bevel angle than most reloading component primers.
Winchester primers can usually be identified as factory due to the primer markings. Most of their ammunition presents machine marks on the primers that look "whispy" due to being dragged along in the assembly process. Why theirs have them and others dont, I couldn't tell ya. Some of the older winchester rifle styles have this too, while newer styles do not.
On most of the bucket you can't identify right off, compare the primers to factory loads of the same headstamp if you have them, and examine the cases for parallel sets of case-length "scrapes".
These usually occur more severely when a fresh and warm fired brass case is extracted against a rough steel chamber wall. They occur most often when chambering a round that is not perfectly centered on the bolt, and only finds center after a ride across the breach face, finding home when the round is fully chambered. Theres a litany of other parts that brass can drag across in chambering in different rifles, I cant possibly list them all.
You can also observe extractor dents near the case head on most brass. They will be rotational axis dents, instead of case-length scrapes. These usually present even in moderately well cared for brass, whereas discarded brass thats been cared for very well often does not have case-length evident scratches to an unaided or inexperienced eye.
Multiple sets of scrapes usually indicate multiple chamberings. While not an exact science, you'll quickly get a feel for what looks good, and what has obviously seen substantial use about halfway through the bucket sort.
If you come across pieces that look unusually well cared for ( obviously not factory) and have been "abandoned" while scrounging for brass....put those in the recycling bucket straight away. They are probably there for a reason, as the care required to maintain cases properly is not often freely abandoned until very near the end of the usable life-cycle, if at all.