I recently purchased the book "
Colour Case Hardening of Firearms" by Seim. Based on my quick skim of the contents, what is real case hardening, is sort of like, what is real barbecue. What I remember from my metallurgical studies was that case hardening was an infusion of carbon into the surface of steel, to increase the hardness. Salt baths and gas infusion seem to have replaced the old bone/leather processes, and from what I have seen on the web, pretty colors are not important for gears or drill bits.
Piston rings case hardened, oil tempered
The case hardening we see on firearms is pretty case hardening, maybe it did something metallurgically good on pre 1920 carbon steel firearms, but today, with alloy steels, it is definitely decorative. And I think the pretty case color on vintage arms was deliberately done to enhance sales back in the day. They could have hardened the surface without pretty colors.
Color case hardening is a skilled process. Seim shows all sorts of fixtures, copper wire wraps, the ingredients used are well known, but the "secret sauce" used by successful case hardeners is on a need to know basis. Those eye popping Trunbull colors were achieved by hard work and experience with particular firearms.
If the alloy is known, the case hardener can whip up something, because he has done it before. But as Seim says, the post 1964 Win M1894's have a poor reputation because Winchester changed its alloys and did not tell anyone. Winchester was making these as cheaply as possible and had zero concerns about the wants of owners 50 to 60 years later.
I do believe all case hardening colors are delicate and the modern firearms I have that appear to be genuine color case hardening, there is a clear polymer coating over the case, to keep it from being worn off. I do not know enough about which modern firearms have bone/leather case, versus firearms that have surfaces created by other processes.
I was surprised to find that my H&R Topper has "real" case hardening, a cyanate salt solution was painted on prior to case hardening and this accounts for its colors. To some, that might not be real case hardening, but it is pretty.
This is my M1885 and the color picture is kind of fuzzy. I think Winchester/Miroku picked steels that produced pretty color case hardening colors. I have not seen a Trunbull M1885, so I don't know if the Trunbull colors are more vivid and eye popping. I have not tried to rub the case off so I can not speak about the durability.