What make of rifle is it? Those look like laquered cases. Although I've never been able to get the laquer to melt off of the cases, using a torch, the are a bit stickier than the poly stuff. I believe they are anyway.
I just can't figure out why it's so stuck. On the other hand, trying to hammer it out with an aluminum rod and failing may just make it seem to be more stuck than it actually is.
I'm glad that it was a spent casing, because I had assumed that when I posted my last post.
Bushyguy, that was a good catch. I didn't think to ask.
That acetone/tranny fluid deal might work, but I don't know. If the Kroil didn't penetrate it, I don't know what will.
OK, back to the make of the rifle. Some have chrome lined chambers and some don't. Those without may have a bit of a rough chamber surface that can exacerbate the situation.
The bottom line is that if it went in, it's gotta come out. Get yourself a steel cleaning rod and don't be shy about giving it a decent whack or two. If your barrel is not chrome lined and it happens again, you might just want to stick to something that isn't lacquered.
Do you have a heat gun? If you do, you might want to hit the chamber area, after removing anything that will melt, with heat to see if you can get the steel the expand a bit and maybe soften whatever is holding the casing in there. To be clear, I'm not talking about a hair dryer, but a heat gun. I got mine for around $13 at harbor freight. Every home shop should have one, along with duct tape. LOL.
Since you're trying things, WD40 couldn't hurt. Not much of a lubricant, but it penetrates. Just don't put anything flamable down the pipe and then heat it. That might get interesting.