I would have to agree with Walkalong that Longshot is probably not an ideal powder for this caliber. From my experience using it for a different caliber (38 Super) it tends to only work well (complete burn) with heavier 158gr bullets out of my pistol, 100gr would not reach an adequate pressure for good burn and would hit a velocity plateau and leave unburnt powder in the barrel (just like your friend). Here's what QL estimated for a general idea for 5.6gr of Longshot:
Actually, that looks pretty damn good for what I want; a high velocity 40gr load for the 16" barrel.
That chart is pretty close to what velocity I hit in the 16" PS90 barrel. 5.6 gr was showing pressure signs on the primers (using the thin cup CCI 400's). The velocity is in the range of what I want. If I re-work the load with thicker primers (Federal, arsenal #44, or Remington 7 1/2) the primers should stand up to a little more pressure without blowing out.
The downside is the arsenal #44 and remington 7 1/2 primers are a bit hotter so the pressure curve will hit more rapidly. That *might* make the load a bit more suitable to the pistol (with a slightly reduced powder charge), as it'll ignite the powder more rapidly. The idea of using magnum primers is not about igniting a big charge fully, but rather, getting the burn going more rapidly on a smaller charge. That should get it scooting right along in a shorter barrel.
I have to conjecture here but I believe the load that popped that primer was in the 5.8 or range, or .2 higher than the RCBS 1500 scale indicated. That's the most I've ever measured the RCBS 1500 being off. It happens when you trickle powder slowly in to the pan. The scale tries to average out and "hold" the current weight. The noise reduction algorithm they have in the scale works against you if you don't drop powder fast, makes it less accurate than it really is, without the programming "help" they gave it.
The only way to get it back to a true reading is to empty the pan, hit zero, and then re-weigh. (This is where I've found charges .2gr off from previous reading. simply removing the pan and re-seating it *sometimes* works but only if it's .1 gr off. If it's .2 gr off I've found you have to re-zero the machine to get it back to normal).
The chart from Quickload show really backs up the burn rate of Longshot being more ideal for the PS90 rifle than the FiveSeven pistol. (For the same reason you were finding it wasn't ideal for 38 super; too short of barrel.)
I'll keep experimenting in it with the PS90, go through the primer combinations, and see if I can get the spread down. The powder is fully burning in the 16" barrel, so now it's just a matter of getting the right amount of flame on it to even it out. (Not the first time I've fought a velocity problem with CCI #400 - I stopped using them on 223 a couple years ago for the same reason as I couldn't get Varget to ignite good and even with them. Remington 7 1/2 did it much better / more reliably.)
Dunno. The whole point of the scientific method is to postulate and prove (or not). I've postulated. Now we get to see what the test shows. As always failure is an option.