Grains is a unit of weight, or mass. It is not a unit of volume. The idea of grains/volume is a construction made up so Black Powder subs such as Pyrodex, which weighs less than Black Powder, could be safely loaded.
No Idea Where You Got This ???
Original gun powder [black powder] when it began to be used in small arms, was measured based on the
Avoirdupois system where the pound was divided by 16 into ounces, and the ounce was divided by 16 into drams, and thus the pound defaulted into 7680 grains. Elizabeth I, adopted the Troy system smallest unit of measure, the "grain" and when she switched from the Troy 12-ounce pound (5760 grains) to a pound with 16 ounces...it made the pound 7680 grains.
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The new system under Elizabeth was very similar to the
Apothecary's Weight system which in England was aligned in part with the old Troy Weight system. Although the Apothecary's system used
liquid ounces and measured
by the volume of that ounce, it's smallest unit was
the minim, which was equal to the dry unit of weight,
the grain. Over time as small arms developed, using volume containers based on fluid ounces to measure gunpowder came into effect, and this was centuries ago....long before Pyrodex. Since grains and minums were the same, it was easy to adapt volume measures of one
scruple, being 20
grains, or variations based on the smaller grain/minum to use when loading gunpowder.
BUT when smokeless was invented it was discovered that there was confusion over loads because the new powder was not interchangeable, AND because a lot of the previous measuring devices were not very precise. The imprecision didn't matter with black powder, because a variation of a grain or two from a weighed amount vs. a volume amount didn't make a huge difference in pressure or velocity....i.e. if you wanted to shoot 40 grains of powder by weight, but your measure tossed 45 grains because the amount was "rounded" instead of a "level measure"..., normally was not a problem. Plus black powder differed in weight from maker to maker depending on formula, the ratios of the three components varied from country to country, but due to the inefficiency of BP as a whole, it didn't matter enough to the small arms shooter.
With smokeless powder, however, being off by a few grains might be a real pressure problem, and confusing the two powders was even worse. Imagine the old .44-40 round using black powder at 40 grains, being reloaded with 40 grains of cordite.
While at the same time the .30-30 cartridge came onto the market not using 30 grains of black powder, but 30 grains of smokeless powder.
So today, as in centuries past, one loads the antique techonolgy with a measure based on volume using the liquid
minim which was once equal to the weight of the
grain. Over time the Avoirdupois system was made more precise, the ounce went from 480 grains to 437.5 and the pound went to 7000 grains. So today the Apothecary ounce is different from our Avoirdupois ounce.
The grain is still, however the grain, and we are now so precise that we measure in 10ths of a grain when loading smokeless powder..., by weight.
LD