Keep in mind that the A-weighted scale (dBA) will probably be more reflective of actual damage potential than the unmodified dB scale. Also make sure different sources use a consistent distance from the source, and preferably place the mike near the shooter's ear rather than, say, 1 meter in front of the muzzle.
Straight comparisons of hearing protection efficacy are difficult because the NRR ratings are based on continuous low-volume tones at the threshold of hearing, whereas a gunshot is a much higher-level impulse noise of extremely short duration. Also, the NRR doesn't really take into account the way a given set of muffs or plugs fits your head/ears; the quietest muffs I've ever used are Peltor Shotgunner low-profile muffs with a NRR of 21 (IIRC), while my wife's high-dollar liquid-filled-earcup muffs with a NRR of 29 allowed a lot more of the high-frequency transients for me, and my ears would always ring just a tad after using those.