I had 700 cases of LC 308 brass ruined by old surplus powder. I loaded the stuff, but the powder went bad in the case, emitting a gas which corroded the base of the bullets and caused case neck cracks. So I pulled all the expensive match bullets, dumped the powder ( on the lawn). But I had all these nice CCI #34 primers in the cases.
So I deprimed the cases. I used a Lee depriming die, the top of which is vented, more or less. I raised the ram lightly until the pin rested on the primer, then lightly pushed the primer out.
I saved the primers and am using them, quite successfully, in blasting ammo.
This experience was much better than depriming about 500+ rounds of WWII 30-06. I was given unfired primed brass. The first owner pulled the bullets and dumped the powder.
These primers were corrosive and crimped in. The crimping made it so much more fun. At least one out of 20 primers would not come out, would stretch so much that the decapping pin would pierce it. When that happened, BANG!. A flash of flame, a waft of smoke through the top of the die and the cats would run for the exits. Unfortunately I could not get the fired primers out of the pockets. Tried all sorts of things, nails, hooks, etc. They were crimped and were not coming out. So I had to toss out an otherwise good case.
I wore safety glasses all the time I was doing this.
When I finished, I cleaned the decapping die with hot soapy water. I removed the crimp from the good cases with a Dillion crimp remover, ran them all through a sizer, trimmed them all, and they are ready to be used. All is well.