The PPM is an easy fix, ArchAngel14. Unscrew it and lap the cone to the body with some rubbing compound. Unless your PPM is really buggered, this should stop the leaking, even with fine ball powders.
If you're still unhappy with the accuracy, try changing your technique. There are some weird things people do with a thrower with good intentions, but which actually make the precision worse.
1. Tapping the measure between each throw. Also banging the thrower arm to the stops, forcefully.
This is detrimental to accuracy. When the powder falls in "loosely," it's as accurate as it's going to get. As the powder falls in free air, it arranges in a relatively random pattern. Thousands of flakes of powder arranged at random is going to end up fairly consistent. If you tap it so it packs in there "tightly," the throw is going to vary by how much pressure there is packing it in. I.e., as your powder reservoir goes lower, the charge weight will decrease. An analogy would be measuring a cup of snow. Sure, you can pile a huge column of snow over a cup and keep on tapping until you get a cup of ice. But your pressure and vibration are going to vary. So cut your losses and stick with what drops, naturally. This is actually covered in the PPM manual.
2. Leaving the arm up between throws.
People think this is better, because it gives the powder more time to settle in the measure. Well, for the same reasons as #1, you shouldn't do this. In addition to how high the hopper is filled, you're also now packing each charge more or less, depending on how much vibration you are exposing it to, everytime you bump your bench or whatnot.
Leave the arm down between throws. Move it up, smoothly. Move it back down to drop the charge. You don't have to sit there and wait a few seconds for the measure to fill. It only takes a split second. Leaving the arm down provides a second benefit. If part of the throw got stuck in the measure (maybe just a few lingering flakes, or maybe worse), you might actually see it fall while you're getting your next case. If you immediately raise the arm after you drop the charge, you are destroying the evidence.
If you can't get the accuracy you want from the Lee PPM, then pony up for a Chargemaster, or the like. Cuz it doesn't get any better.