Many thanks for all the input, and Happy New Year to all on THR.
Concerning the powder (PCL 531) : I have been using it wihout any problem for a while now, as being interchangeable with W-231.
Depending on exact bullet shape & material I have loaded lots of :
.45 Colt / 250 Gr : 7.2 - 7.5
.44 Spl / 240 gr : 5.0 - 5.3
.38 Spl / 148 gr WC : 3.0 - 3.3
and that fateful .38 Spl /158 Gr : 4.0 - 4.3
A too light charge ? A .38 solid based "button-nosed" wadcutter,when seated properly, takes up about as much space in the cartridge as a 158 gr LSWC & I load those with 3.3 gr ( a full grain less) of the same powder, without any "flash explosion" or "detonation" or whatever.
I too do suspect that this phenomenon is sometimes used as an excuse for a double charge or otherwise sloppy reloading. Some knowledgeable folks however, whose opinion I value, respect and trust (Mike Venturino, for one) claim to have witnessed it.
Report & recoil with my overload were very noticeably heavier than from a regular.38 Spl/158 Gr load but nowhere near even a mild .357M out of a heavier revolver (S&W 586).
Any and all explanation for my scary experience is post-factum speculation, anyway.
No, it was my own "human error" pure and simple. I have nothing or no-one to blame but myself.
Lesson learned : I'll be even more careful when loading & pay even more atention to every detail.
Getting a new cylinder would (here in Belgium) involve turning the defective cylinder officially in for destruction -at my cost-, obtaining a new "permit to purchase a firearm" (costs 85.00 Euros), ordering a cylinder & having it fitted (about 300.00 Euros) & having the entire gun re-proofed - again at my cost-. I think I'll pass & look for another used but fine Mod 14 . They can sometimes be found for 200.00-250.00 Euros.
Someone (AK103K) mistook my PPK for a grip-squeeze-cocking Heckler & Koch P-7 I think .
If my PPK "slam-fired" because of a primer not being correctly seated, I had nothing to do with it: I used factory ammo in that one. Because it is so rarely used, maybe some oil/dust mixture coagulated & prevented some lever or other (lots of those in a PPK) to function properly. I' ll clean it really well & try again.