How are nickel cases better than brass?

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"If nickel was so hard, why would an ammunition company put it on the outside of a bullet?"

Don't forget, many of the early (and very high quality) smokeless military round nosed bullets were "Cooper Nickle" in design. I have pulled a number of these bullets, swaged them to ensure they are all the same diameter, and loaded them in new brass. Accuracy has been very good. Some of the pre-WWI Mauser bullets (.318 bore) even had beautiful hedstamps on the basses of the bullets, where the lead was exposed. That's craftsmanship!
 
Interesting comments, I think the main question has already been addressed as to the pros and cons of Nickel plated brass. However reading through I did see a few errors I would like to address. I should start by saying that I am an Aeronautical engineer, not a materials engineer, but I do have a generalized understanding of materials and their properties.

Electroless nickel plating has a Rockwell C hardness of up to RC-55. This is much harder than mild steel and harder than many tool steels.

This may be untrue when applying to the nickel plating of cartridges, Most cartridges are normalized, this means they are heat treated by heating then steadily cooling to release internal stress. This process would put its hardness at the lower end of the range. Also many reloading dies are made of Tungsten carbide (which has a Rockwell hardness of Rc 75 – Rc 80 ) Regardless a smart reloader should debur the inside of the case mouth with a brush prior to loading. According to the Mil-HDBK-5 (Mil handbook, which we use to define metal properties in engineering) has the hardness of each. There is a vast range of harness depending upon how the steel was heat treated. I
don't know what type of heat treatment they use so I will not try and “guess”. But based on the application, both would be at the lower end of the hardness spectrum. Most rifle barrels are made from either AISI 4140 (carbon steel) or AISI 416 (stainless steel) The hardness according to Mil-HDBK-5 is as follows:

AISI 4140 : Rb 93 - Rc 50
AISI 416 : Rb 85 - Rc 39

Electroless nickel is added mainly for corrosion resistance, but also because of its lower friction coefficient to increase reliability from cycling. it does not need to be hardened so it would be at the lower end of the spectrum. Most cartridges are "normalized" meaning that they are heat treated with low heat and long term cooling, also reducing hardness, but increasing ductility.

From Mil-HDBK-5:

Normalized Electroless Nickel : Rc 49


You could also make the argument for the potential of increased bolt thrust. From my experience with nickel cases it seemed to have less stretch. In my mind I figured a brass case would stretch out and grab the chamber walls better than a stiffer nickel plated case. If this is the case it would cause more stress on the bolt lugs than necessary.

This is not necessary true because the pressure inside the cartridge is still enough to “fire form” the cartridge. The difference would be that it would occur at a higher pressure than the brass case. Internal pressure should peak at the same for both cartridges (brass and nickel plated brass)



Also, once you fire the case, the rougher nickel on the inside of the case is heat treated. I don't know if anyone's ever done a test on the hardness of the microscopic particles after firing, but I'd bet they're harder than the barrel.

This is incorrect. Heat treatment increases hardness of a metal by changing the crystalline structure of the metal. It is changed depending on how hot, how long, and how fast you cool the metal. The heat transfer from firing a bullet is not enough to heat the metal up to a temperature where it would change the crystalline structure. So no it does not heat treat the case.

I doubt a piece of the nickel would do any damage to the barrel for a few reasons: 1. A piece of any significant size would just scratch the copper jacket of the bullet, anything small enough to break off would most likely be so small that it would not do any significant damage. 2. The plating is so thin that it would most likely sheer of upon entering the barrel. Depending on the nickel used, it may be harder, but steel is stronger. But these are just guesses, as there are too many unknowns for me to form a solid answer.


For the original poster:

I like nickel cases for the following reasons:
- They don't corrode easily
- They allow me to distinguish between 2 loads of the same caliber (1 in brass and 1 in nickel-brass)
- They are easier to find at the range when picking up
- They look "cooler" :D
 
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I use nickel when I load BP cartridges. This way I can tell them apart from the smokeless ones.
Also, brass and BP don't mix....The brass becomes black and next to impossible to clean. Nickel is clean in a few hours.
They split much quicker, 3 to 4 reloads, but that's no big deal really.
 
This is incorrect. Heat treatment increases hardness of a metal by changing the crystalline structure of the metal. It is changed depending on how hot, how long, and how fast you cool the metal. The heat transfer from firing a bullet is not enough to heat the metal up to a temperature where it would change the crystalline structure. So no it does not heat treat the case.
You are correct in that the heat generated from shooting will not raise the temperature enough to affect the steel. If it did, there would be some serious problems.

I do want to point out that heat treating is not confined to a hardening process. There are a number of processes that fall under "heat treatment" that perform various functions to increase hardness, decrease hardness, increase ductility/toughness, place phases/elements in solution, etc. While the quench process that is used to harden metals is a heat treatment, it's not totally accurate to say the reverse without specifying the purpose (sort of like a square is a rectangle but a rectangle is not a square).


A piece of any significant size would just scratch the copper jacket of the bullet
+1. Because of the high difference in hardness between the copper jacket and the hardened barrel, any particle between the two would cause most, if not all, of the damage to be done to the softer copper.
 
I do want to point out that heat treating is not confined to a hardening process. There are a number of processes that fall under "heat treatment" that perform various functions to increase hardness, decrease hardness, increase ductility/toughness, place phases/elements in solution, etc.

I did not say that it was confined to just changing hardness, also that it changes ductility. I used hardness as an example because that is what we were concerned about in the previous discussion.

Heat treating will always change hardness, ductility, resilience, tensile strength, elastic modulus among other things. Generally you are looking for one specific attribute to be increased. (i.e. if you want to increase hardness, generally ductility and tensile strength is reduced, but hardness and resilience is increased. There is no way to just change one.......which is why composites were invented :D )

While the quench process that is used to harden metals is a heat treatment, it's not totally accurate to say the reverse without specifying the purpose (sort of like a square is a rectangle but a rectangle is not a square).

not quite sure what you meant by this.
 
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