I remember that mythbusters did a test setting off different pistol calibers outside a chamber and the only one that did any damage was a .50 (not sure if it was BMG or not).
I'm pretty sure it was a .50 BMG, and being so large, the flying cartridge case did some damage to the oven it was being cooked in (the bullet hardly moved because it's much more massive).
The reason they gave on the show was that since it's set off in the open, the pressure doesn't get nearly as high as if it's in the barrel.
Sure, because once the bullet and case are separated, there is no longer anything to tightly contain and direct the gases being generated--that's why barrels are so important.
However, in general I wouldn't take anything the MythBusters say regarding physics seriously, even when it concerns firearms. They've gotten so much wrong--sometimes dead wrong--over the years, and I think they could really use a consultant in such matters. Take for example the episode in which they tested whether it is possible to make bullets (fired out of smoothbore barrels) curve by swinging the gun around like in the movie "Wanted". To start with, the idea is so silly that it's not even worth the effort to test because bullets will always travel in a straight line due to inertia and a force would have to be applied
as it is flying to make it curve. In short, it's not possible to do it that way. Well, DUH!
So they set up a test anyway, swinging their guns (also with a mechanical arm!) and firing through three sheets in order to see whether a laser can pass through all three holes, which would indicate a straight path. The result was that the laser did pass through all three holes of every shot, which led them to conclude that the bullets were flying absolutely straight. Well, they may have accidentally gotten the correct answer, but they forgot the fact that the bullets are in fact curving downward because of gravity, which shows how useless their test was to begin with due to imprecision. :banghead: Actually, it's even more complicated than that, but I've digressed enough as it is.
Now these were all pistol and rifle cartridges which contain far less powder than a shotshell.
I wouldn't say that a .50 BMG cartridge contains less powder than a 12-gauge shotshell.
There are pistol calibers that are more energetic than 12-gauge, as well, which implies they contain more powder.
http://www.youtube.com/watch?v=40ylCFeMbgw
Shotgun shell being ignited on a table by a BB or pellet.
Keep in mind that this is not the same scenario as any in the original post. The lead shot had been removed, for one thing.