Maybe it lost something in the translation concerning the valve springs. The point being that a properly designed spring, operating within the yield values is the steel, works forever. If you have crappy springs, in a mag that pushes the steel past it's yield, you will have problems.
Exceeding yield will cause problems, I agree with that. However, staying below yield is not a guarantee of performance. I'll explain this further below.
The thermal relaxation phenomenon occurs at the lowest reaches of the tempering curve, right? So wouldn't that be several hundred degrees, minimum?
Yes and no. There are different metallurgical mechanisms at play - the scenario you reference is one of them, and will certainly result in relaxation. However, it is not the only way relaxation occurs. Other mechanisms are either thermally activated or have a thermal component, but they are also active at room temperature.
It’s Saturday morning and I have some time to explain this further, so be warned – wall of text ahead.
If the temperature is near or over the tempering temperature for steel, further tempering of martensite will occur. Martensite tempers as carbon diffuses and subsequent phase transformations occur. Phase transformations will relieve some of the stresses.
When closer to room temperature, other mechanisms cause relaxation. A major one is transformation of metastable phases due to the addition of strain energy. Metastable phases are present in most any steel. Examples are martensite, which is a key phase used to strengthen steels, and retained austenite, a high temperature phase that is stabilized enough by alloying to stick around at room temperature.
These phases are stable enough for practical purposes, but are not at the lowest energy state and will transform if given an opportunity. Strain energy introduced by compressing a spring is enough to push the phase over the edge so to speak, and cause some fraction to convert. This is addressed in
About the Structural Mechanism of Stress Relaxation in Metastable Alloys, by Grachev. Here are some excerpts from his paper which may help explain:
At the initial moment of loading the entire strain is elastic, i.e., ε0 = εel . With growth in the hold time a part of the elastic strain transforms to plastic strain.
For alloys with a high portion of metastable phases, like steel, there is a time-dependent component to elastic loading. It’s not as sudden or pronounced as with polymers, but some of the initial strain (ε0), which is elastic (εel) and fully reversible, will turn into plastic strain (εpl). This means that a loaded spring which has had any amount of its elastic strain convert to plastic will not fully restore to its original condition when unloaded. Therefore, it will have taken a slight set and lost some of its force.
Here’s one of Grachev’s graphs showing relaxation over time for a certain steel alloy at various elevated temperatures. The y axis shows relaxation as σr/σ0, or the relaxed stress (after a period of time) over the initial stress. The x axis is time in minutes.
It’s pretty clear that the amount of stress lost in the spring increases with increasing temperature. It is important to note that the loss is not sudden - this is not a case of yield strength being exceeded! There is a gradual loss of strength to an approximately stable level. This behavior alloys the educated or experienced designer to account for relaxation. Transformation or decomposition of martensite is the likely cause for relaxation in this case. A very important note is that this behavior can vary drastically from alloy to alloy, and even between different heat treated conditions of the same alloy – this is only one example (hardened U8A steel).
Here’s a particularly interesting example from the same paper. This one is a 70S3KhMVA steel which has some degree of retained austenite. As the temperature decreases from 20C (68F) to -196C (-321F),
more relaxation occurs – completely backwards from the previous example. How does this happen?
As noted earlier, austenite is normally a high temperature phase in steel – in a plain carbon steel, temperatures of 1333F or higher are required to make it appear. The addition of certain alloying elements can stabilize austenite enough to be retained at room temperature. Further cooling forces the transformation of this metastable phase to proceed. It’s not necessary to hit -321F to transform – this is an extreme case used in the paper. In this case, a fully loaded magazine exposed to a North Dakota winter could actually lose more strength than one seeing an Arizona summer. Retained austenite is very common in hardened steels, and is usually present to some small extent. Most of the time it’s not an issue, but bad heat treatment, improper material selection, etc. can result in more retained austenite than desired.
The American Society for Testing of Materials (ASTM) released a collection of Selected Technical Papers (STP) specifically concerning stress relaxation testing. In ASTM STP676 is a paper titled
Room-Temperature Stress Relaxation of High-Strength Strip and Wire Spring Steels – Procedures and Data, which contains the above graph for room temperature stress relaxation of a strip spring steel (not coiled wire). The difference in behavior between alloys can be seen pretty clearly.
I’ve thrown a lot of information out here, and hopefully it’s enough to help show what happens in a loaded spring. There are a lot of variables in relaxation of springs - design, alloy, heat treatment, service temperature - but it has been known for decades that relaxation does happen. In a properly engineered spring, the user would never know the spring lost force because the design accounts for this phenomenon. There are companies and designers out there that, for whatever reasons, are unaware of things like this – as such, there will be good and less-than-good magazine springs floating around.
Just because some springs work flawlessly when loaded for an extended period does not mean every spring will. The fact that so many people in the gun community debate this really goes to show that by and large, the magazine spring designers are doing a very good job. However, cases of weakened springs pop up with some regularity.