You need to get a chronograph. Trust me. Don't just follow other people's recipes. Just because X amount of powder behind a Y weight bullet shoots Z fps in someone's rifle, doesn't mean it will shoot the same fps (and accuracy) in your rifle. I've got 3 M1 Garands that shoot with varied average muzzle velocities. IE, my SA with a SA barrel shoots consistently 50 fps slower than my HRA with an LMR barrel.
That said, I'm assuming when you refer to military match loads in the .30-06 that you are loading for the M1 Garand. If so, the sweet spot for 168 or 175 grain bullets at around 2550 fps. 45gr is a starting point. Work up from there.
I don't reload for the M14, which I'm assuming your reloading for since you make reference to military match loads, but 41.0gr is a good starting point for .308 loads in 168.