It's not unburned powder you are seeing. It is actaully a form of ash that is created. Sometimes you can take a brass case and dump it out after firing. You will see that even though it looks like kernels it won't ignite. There are much smarter ppl than I that have shown and proven that the muzzle blast is from gases. Slow motion video also shows that there isn't unburned powder. I use to think the same thing when I saw kernels falling out of my revolver.
I almost lost a bet on this ^^^^ well I did ,but the RO at our indoor range wouldn't take my money,
I was shooting right up to close and help clean up , the RO was sweeping the range in front of the shooting bays , and said "I wonder if you could load up this unburnt powder" he was joking, and I said " that's just ash , the powder is all burnt up before the bullet leaves the barrel and the flash is the gas hitting air" he said the flash is the gas hitting the air, but this unburnt powder comes out after that , I asked if he had ever tried to light it ? he said no, but go ahead and try , I asked if he wanted to put money on it , he said he wouldn't take my money ,
there was about a 2lbs pile of dirt, ash , powder? sitting there , and just incase he was right (and seemed to think he was) I scraped about a 1" high by 4" pile away and lit it , it sparked a bit at first , then took off just like fresh powder , , started slow then real fast , with bright flame and the smoke was just like I had just shot 20 rounds down range ,
sure glad I didn't light the whole pile
our indoor range is handguns and rimfire only and a lot of hand loader's , lots of 2400, W296, Bullseye, W231, AutoComp ,... with lots of long barreled 44's, 357's, full sized 45's not many 2" stubbies
next time I'll take pictures, as I didn't think there would be anything to take a picture of .