Burn rates are a very unreliable way to choose a powder. Burn rate charts rarely show powders in the same order and very often the same manufacturer will change the powder positions on their charts from year to year. If you want proof of their unsuitability for safe powder comparisons simply read the burn charts carefully, you will usually find a warning somewhere on the chart that tells you to not use the burn rate chart for selecting a reloading powder. For example, the Accurate powder's chart states;
"Burn rate charts can never reflect the differences between powders in the correct proportion, and can only place powders in approximate burn rate envelopes.
NEVER USE THESE TO DETERMINE/CALCULATE LOADS - ALWAYS REFER TO REPUTABLE LOAD GUIDES/MANUALS."
Manufacturers most often test burn rates by performing a closed bomb test. A measured amount of powder is deposited in to a closed metal container and ignited. Instrumentation measures the pressures, temperatures, and burn time. There are no universal standards for this test and variations in ambient temperatures, barometric pressures, volumes, etc. will cause the results to vary, this is why burn rate charts from different sources will not match. Also, no two batches/lots of the same powder will burn exactly the same, that's why the manufacturer of a specific powder will move the position of their powder relative to other powders from time to time. Put all of these uncontrollable variations together and you can see why burn rates are a poor yardstick.
But for the layman burn rate charts are better than just guessing although I'd recommend reading the manufacturer's recommendations and their reloading information as a primary guide as to what is safe. If the manufacturer doesn't show powder charge information for the cartridge you are trying to build then I'd avoid using that cartridge combination - unless you have verified/first hand knowledge that the load will work. For example, Hornady shows a load using their 110gr Vmax bullets over IMR 4198 for the .308 Win but it's not listed in their Service Rifle section, but I've used that load in my M1As for years with no issues (and it's a very accurate load). While it's not recommended by Hornady I've found no reason to not use it.
I use QuickLoad to help develop my loads. One guideline I like to use is the amount of the usable case volume that the powder uses - the filling percentage. I wont use a powder that will result in less than 50% filling. Years ago IMR came to the conclusion that .30 cal rifles seem to work best when the usable volume is filled to between 93% to 98% and I try to use that guideline for just about everything that I load, including pistols. High fill volumes will prevent you from getting double powder drops and I subscribe to the theory that it prevents unexpected pressure spikes due to unreliable flame front progression through the powder charge. There are powder choices that will work but result in low fill volumes and I'd avoid them. I also avoid compressed powder charges, especially with ball powders. I don't crimp and a compressed charge can push the bullet out of the case which can change everything about the cartridge.