More then likely your chamber is badly fouled with hard powder fouling, or has rusted at some point.
It is difficult to clean the chamber on those rifles using common cleaning methods.
First, I would round up a jointed cleaning rod long enough to reach through the barrel without the handle section screwed on.
Next, you need a .45 Cal. bronze bore brush, some Hoppe's #9 solvent, and and an electric drill.
Run the rod down the barrel and screw the brush on the end through the ejection port.
Now chuck up the rod in the drill and squirt some solvent on the brush.
Turn the drill on and really work over the chamber to get out any hard fouling or rust.
If that doesn't cure it, the chamber is probably pitted and will need to be polished.
I'd probably leave that to a professional gunsmith.
BTW: It is a very dangerous practice to leave oil in a High-Power rifle chamber. That increases bolt thrust all out of proportion to what the action would normally be subject to.
rcmodel