DITTO!They will after you've worn thru the nylon coating by not using a rod guide. Buy a rod guide.
Bore Tech Eliminator, as already posted, is non ammonia and is great for copper. I have gotten away from all the ammonia based copper removers, although they work just fine.
One thing that gets some people stumped at first is the fact that the carbon and copper fouling is often "layered". It may take using copper solvent, then a good product for carbon, then more copper solvent etc. The barrels that have not been cleaned in a long time are often a B**** to get clean. A bore scope will tell you what is on the surface that needs to be attacked. A casual brushing in between steps and a good rinse helps. Lots of patches. (Yes, we do need those stinking patches)
Clean often and avoid the headache.