Detonation!!
There's some people in Finland, where silencers are legal and they experiment with subsonic loads:
http://guns.connect.fi/gow/gunwriters.html
Now on with the topic:
=============from:
http://guns.connect.fi/gow/QA1.html
1) "When Lady Luck kiss you goodbye, it is still goodbye!" As small charge of powder as .2 gram or 3.1 grains of shotgun powder is able to blow up action of a .308 Winchester rifle. (My empirical knowledge is based on test-shootings with .308).
That charge is half from definitively minimum load with a jacketed bullet, weighing 123 grains/ 8 grams and about one third from a safe minimum charge for .308 Win. with 170 grains / 11 grams jacketed bullet. The very same .20 gram / 3.1 grains is good, safe and subsonic charge for .308 Win. with a cast, lubricated lead alloy bullet with nominal weight 93 grains. Powder used for test-shootings was Finnish VIHTAVUORI N 320 (a most close counterpart of German blank-cartridge powder, adopted in 1933 and used as a propellant of 7.9 x 57 mm Mauser subsonic "Nahpatronen", loaded by Finower Industrie GmbH during WW II).
Two known accidents were also happened with reduced charges of that same powder by S.E. Effect. One with halved Definitively Minimum Charge and another with third D.M.C. Charge was in both instances before mentioned .20 gram / 3.1 grains. Bullets were - of course - jacketed ones, weighing 123 grains and 170 grains.
According to my test-shooting records is one full gram / 15.4 grains of N 320 safe charge behind both of these bullets in .308 Winchester cartridge with a standard (non-Magnum) Large Rifle primer. Powders N 310 or CLAYS are as or more easy to ignite as N 320, and so fit for use in reduced charge loads. This is the very most important quality of a powder, when the subsonic muzzle velocity is aspired after. Fast burning-rate and clean burning of powder are also beneficial - if not essential - properties.
An overly-reduced charge is a good way to court disaster, but reduced charge detonations are never (?) happened with a first shot of a string, when the rifle bore is still clean and at least slightly moistened with oil or grease. Risk of S.E.E. is increasing when the bore is fouled with carbon, lead dust from primers and unburned powder kernels, when the oil or grease is shot away from the bore.
First signal of imminent danger is increased variation of bullet velocities. A bullet, lodged into the bore, scares me always to have nightmares in seven to fourteen next nights... Velocity variations are usually not progressive but undulating because of variable bullet friction in the bore. Especially that friction (hardness) of jacketed bullets tends to vary, when the powder pressure behind them is low. Unfortunately this pressure cannot be higher, if one is trying to get subsonic velocity with each & every shot from the rifle, giving usually Mach 3 readings of bullet speed - like .223 .
A main reason of S.E.E. is disorder of powder ignition. Powder charge does not burn after the explosion of a priming pellet. It smoulders like a German tinder, developing a cocktail of explosive gasses like nitrogen oxides, hydrogen (very reactive "In Statu Nascendi" hydrogen - not yet bound to H2 molecules), and carbon monoxide. When this highly flammable mixture of gasses catches fire from still smouldering solid powder remnants, may the "BANG !" be horrible. Mere three grains of gasses may literally wreck the strong .308 Win. rifle action. (Three grains of smouldered solid powder is still three grains of material, despite of it's gaseous form of existence).
Maximum allowed chamber pressure of .308 Win. factory-loaded cartridges is 3600 atmospheres. Case head stands 4000 atm. but the action may be hard to open and the empty shell is usually no more reloadable. Primer pocket may be enlarged and/or the primer blown. Pressure 4200 to 4500 atm. may blow the case head, and the action of many rifles stands as much pressure as the cartridge head; no more.
Severe hand and/or eye injuries of the shooter are possible if the action fails. Eye injuries, including the permanent loss of eyesight, are possible, when the case head fails. This depends on construction of firearm's action, but use of eye protection is always advisable when one is bustling with weaponry. Highest measured detonation pressure was 10 000 atmospheres. A pietzo-electric pressure gauge was broken and highest grade on the pressure scale was this 10 kilobars. A sturdy test-barrel of a German gun-proofing laboratory was wrecked, of course.
This disastrous test was repeated with another set of equipment for the sake of comparison. Pressures of first shots were slightly less than normal. It might be fifth or sixth shot, when the new test-shooting barrel blew up. Again a pressure gauge disintegrated and a scale told: 10 000 atmospheres! It was presumably just a fraction from whole horrible truth, because so called "wave pressure" of a detonation may exceed reading A HUNDRED THOUSAND ATMOSPHERES, when the explosive material is in gaseous form of existence, pre-heated and pressurized before explosion.
========continued at:
http://guns.connect.fi/gow/QA1.html
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