Aha... something that my physics background can answer.
Blackpowder is not a true explosive, no, but, neither are most smokeless. They are compounds that burn very quickly.
Air space in BP Cylinder / smokepole. (between powder and ball)
cap ignites
powder ignites
air (only part being friendly to fire.. ie Oxygen, hydrogen, etc)... some gets consumed by the burn, this will raise pressure a little. The rest of the air will compress. The air compression isnt gonna do squat if the airgap is small.
The problem occurs if you have the ball seated way up front and a relatively small amount of powder. This means that there is a large airspace, this means more oxygen etc, and more non volitile gasses to compress.
IF the ball doesnt give way first and exit the chamber, pressures CAN get high enough to rupture the cylinder.
Air space in cartridge
Primer ignites
Powder ignites
bullet is crimped (if it is crimped) into the case with FAR less force than the burning powder takes to unseat it. You can unseat a bullet with a primer sometimes.
If the bullet doesnt exit the case, the case walls will rupture and vent pressure before any serious harm to the chamber.
Air space in barrel - ie... stuck ball or bullet
THIS IS A PROBLEM!
cap ignites
powder ignites
ball (or bullet) goes sailing down the barrel.
If the barrel has a blockage, be it a stuck ball, or even hardened mud, there will be problems.
The air in the barrel between the station object and the moving bullet will get compressed. This pressure most times will not exceed the force that it will take to move a blockage. There will still be pressure build up behind the bullet that you have just fired. Some of this will vent past the case and back towards the shooter, or will pop the cap off the BP revolver or smokepole. I have seen muskets be recocked when this happens.
The pressure between the two bullets will have nowhere to relieve itself.
Barrel will bulge until pressure drops below the weakness point of the metal.
In OLD firearms, the steel was not as good as we have now and it took less pressure to cause problems.
NOTE - I am NOT stating that you should go out and try any of this.