The effects of canting is simply because of design form.
A bullet or a barrel does not know which way is up or down, or at what point it is oriented to... If you could fire a bullet from a barrel that was just 'sitting' there, in space, and this barrel had no receiver, bolt or stock, and there was no outside force acting upon it...
That barrel could be rotated around the bore center line axis, stopped at 'any' point around this axis and fired... the bullet will act the same, no matter at what point around the bore center line axis the barrel was fired.
Only the center of gravity offset(arm) at certain points(stations), the holding of the firearm by the shooter and the acting forces of recoil(force vector) will cause the act of 'canting' to have an effect on the bullet.