The bolt does not require to be dissembled to check headspace, BUT if the measurement is close the bolt was required to be dissembled. This includes the extractor, cocking piece, firing pin etc. just the bolt body and bolt head were used.
With the bolt completely disassembled the measurement is far easier to check.
The rimed .303 cartridge case does not mean anything as far as headspace goes, the only difference between a rimmed, belted or bottle neck case is the distance from the bolt face to the datum line.
Please note, I have headspace gauges for both the .303 and .308/7.62 Enfield rifles. What I'm trying to get across to you is you do not need headspace gauges to check an Enfield rifle.
Second method for checking headspace/head clearance using a set of Vernier calipers. And the bolt does not need to be dissembled.
Measure the overall length of your unfired or resized cartridge case and write it down.
Next seat a fired spent primer in your test cartridge case using just your fingers. Your going to seat the primer with the bolt face and the amount it protrudes after chambering is your head clearance or air space.
Now chamber the test round and slowly close the bolt and then remove from rifle. Now remeasure the overall length again and write it down.
Now subtract the first case length from the second case length and this measurement will be head clearance or the "air space" between the bolt face and rear of the case.
Now the last batch of new unfired .308 cartridge cases were -.002 to -.009 shorter than minimum headspace or the GO gauge. At maximum headspace you can have as much as .017 head clearance on the enfield rifle.
My Ishapore 2A1 had .012 head clearance and I could fire both .308 or military 7.62 ammunition without any problems. "BUT" the commercial cases went in the trash and were not reloaded because of stretching in the web area. (as did my .303 cases if not fire formed correctly)
Just remember this, the Enfield rifle is not made to American SAAMI chamber and headspace standards and it is also not made to U.S. military M14 headspace and chamber standards. And NO ONE knows what the headspaces settings are for the Ishapore 2A1 7.62 rifle. And NO ONE has bolt heads proofed and tested for the higher 7.62 chamber pressures.