Hildo, i can try to give you same answer, i own a volunteer.
In a breech loading rifle actually you have a hard alloy and the bullet don't upset and expand in the bore, in a old breech loading cartridge, born for black powder propellant the bullet is softer than actual alloy with antimony, in the old 45-70 the good alloy was from 20:1 in the 45-70-500 of the rifle up till a 40:1 in the 45-55-405 of cabine load, the 405 bullet was hollow base, not like a miniè with thin skirt, but a hollw base help to seal the bore, the bullet speed with black powder isn't so high to make the bullet jump the rifle, a 40:1 alloy of lead-tin is enougt with the moderate 55 grains of charge!
Going to the muzzleloader, speaking of small caliber fast twist like volunteer, withworth, gibbs or rigby (volunteer is 1:20, the other are usually 1:18) you must find the right chemistry, a well balanced charge with right hardness of the bullt and weight of it!
A heavy bullet help the expansion due the high mass that oppone to the kick of the blast, in a 1:18 a 540 grain bullet work quite well, (.45) but if you use a high admount of charge, and for long range you need it, the bullet gone straight out to the rifle if it is too soft like pure lead, so for take rifling is use to add a small admount of tin in the lead of the bullet, the right quantity to get a right expansion and a good take of rifling!
Going down with the charge, for example a 100 mt firing line is more usually here in europe (in Italy tere is three or four site with 300 mt line and no one over this) all the balance change, and the research for the good recipe start again!
Pardon my bad english i hope you have understand me!
ciao
Rusty