Yep, I see no reason they shouldn't work once, or they wouldn't sell aluminum cases ammo. I assume these were loaded and had the bullet pulled, but surely they can make one loading. Other than that, there is too much good brass out there to worry with it.I personally would have no issue with the aluminum 45 acp cases purchased pre-primed.
Brass is very malleable/elastic, which is one thing that makes it so suitable. It can be sized and fired many times without cracking. Steel and aluminum can't do that. Brass can be hard at the web where it needs to be and soft through annealing up top where it needs to be more elastic. We also know how to predict when a brass case is no longer suitable for use much easier than aluminum.There are no special properties of brass that other metals can't duplicate. If someone feels there are, I would love to hear them.
Steel and aluminum can't do what brass does, which is why it fails much sooner than brass. For most it isn't worth fooling with, for some it is, with limits.