Are you possibly earing the hammer back further while rotating the cylinder? Is the hammer fully seated in the loading notch?
Incidentally, NEVER DO THIS!
After loading, move the hammer down to half cock, before going to full cock to fire.
After loading the fifth round, or just having the hammer at the loading notch, fully cock the hammer then ease it down all the way. Never leave the gun at the safety notch, especially if loaded.
If the hammer is lowered to the safety notch from half cock position, the locking bolt will rest against the cylinder surface rather than in a locking bolt notch in the cylinder. In this position the bolt will eventually "ring" the surface of the cylinder. After loading, or inspecting the revolver with the hammer in the loading notch, fully cocking the hammer insures the bolt is in a locking notch. Easing the hammer down from this position allows the cylinder to be firmly locked in position.
Bob Wright