Another way is, after removing the wedge stick a wooden dowel down the bore(make sure the dowel lands on the cylinder face between the cylinder chambers and not inside a chamber) and tap the dowel with a rubber mallet. Do it over something soft like a bed, couch, folded towel, panda bear, etc.
That is what I had to do and it turned out it was because the two little frame pins were set out of allignment with the two little holes in the barrel assembly. This was with a brand new Uberti Walker from Cabela's.
If it turns out the frame pins on yours are set wrong I would try to return the gun. If it's just because the arbor is too fat you can probably just sand it down yourself(go slow, be patient and check for fit often). 800 grit is what I have used for this purpose and it seemed to work fine.