It depends on why you want to do it. If it's just to make the muzzleloader easier to load, it's called "coning" and is highly recommended. The bores of many original muzzleloading rifles had a deep, gentle taper (or cone) at the muzzle, which allows the ball to be easily started with thumb pressure and gently seated with the ramrod. There's a simple tool you can buy for this...costs about $40. Just Google... muzzleloader coning tool