Olympic produces much better barrels,
DPMS produces much better upper and lower receivers.
Internals on both guns are fairly decent and Olympic produces a better bolt carrier and bolt.
DPMS uses military specification furniture except for their M4 'Glacier guard' carbine handguards which are not mil-spec and their collapser buttstocks use the commercial diameter extension tube but so does Olympic.
I don't know where Olympic gets their furniture, or if they make it themselves, but it is of a lower quality than the DPMS stuff.
DPMS uses mil-spec buttstock screws, Oly makes their own and I personally think the Oly screws suck.
Both makers use a cast front sight tower, Mil-spec is forged and machined which I consider superior to cast and neither manufacturer uses an 'F' marked front sight tower on their flat top rifles and I have had to use taller front sight posts to get the sights to regulate correctly.
Not a major issue if you are going to mount a scope but very important if you are using a reflex sight, a detachable carry handle/rear sight assembly, and/or a back up iron sight.
Olympics always come with a large aprture/small apeture rear apeture sight, DPMS sometimes come with this correct rear sight and sometimes with a 'Match' type rear apeture sight with two very tiny apetures.
This would be great on an actual Match rifle, especially if the rear sight has verticle stability locater pins and a second spring and detent on the right side which they do not.
A thinner match type front sight post would be nice too.
Without these additions, a rear sight with apetures designed for 600 and 1000 meter shooting is pretty much moot.